How do I set Outlook to require me to select the sending account?

I have two accounts in Outlook. When I send an email it selects the default account automatically. I often forget to change the account and so end up sending business main from my personal email address and vice versa. Is there any way to set up Outlook so that I am required to select which account.

There isn't a built-in way to do this, but this add-in looks like it might be helpful:

http://www.addins4outlook.com/sendguard/...

I've never used it so I can't say whether it's any good or not though.

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